Discriminating Abiotic and Biotic Signatures in Ocean-World Ice via Impact Ionization Mass Spectrometry

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Fabian Klenner and colleagues demonstrate that impact ionization mass spectrometry can distinguish abiotic from biotic fingerprints of amino acids and fatty acids in ice grains ejected from ocean worlds, because soft ionization at encounter speeds around 4–6 km/s preserves the relative abundances of intact molecules, enabling discrimination even in salty matrices with detection limits in the μM to nM range that improve with higher salinity, and with larger molecules surviving better when protected by a frozen water matrix, offering a practical approach for future ocean‑world missions.

Discriminating Abiotic and Biotic Fingerprints of Amino Acids and Fatty Acids in Ice Grains Relevant to Ocean Worlds - PubMed
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Discriminating Abiotic and Biotic Fingerprints of Amino Acids and Fatty Acids in Ice Grains Relevant to Ocean Worlds - PubMed

Identifying and distinguishing between abiotic and biotic signatures of organic molecules such as amino acids and fatty acids is key to the search for life on extraterrestrial ocean worlds. Impact ionization mass spectrometers can potentially achieve this by sampling water ice grains formed from oce …